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If the RAID setup is recognised as a boot device/drive, wouldn't it be usable from NASLite+
Booting is a function of the BIOS. The drivers that NASLite uses target specific range of hardware and are not related to what the BIOS supports. For example, NASLite can boot from a SCSI CD-ROM, however, NASLite does not include drivers to support SCSI or a CD-ROM.
RAID is considerably more complex than that since in addition to the required hardware drivers, NASLite will need to include the necessary facilities to manage the RAID.